|
DATE |
SECTIONS |
PAGES |
EXERCISES |
PROBLEMS |
KEY WORDS |
|
2/2 |
1.4-1.9
2.1-2.3
2.10-2.16 |
9-31
34-38
50-51 |
1.12 + 1.13 +1.14 + 1.19 + 1.21
+ 1.23 + 1.24 + 1.25 + 2.1 + 2.2
+ 2.19 +2.20 |
1.2 + 1.7 +
“draw and name all 5 d-orbitals”
|
quantum mechanics, orbitals,
aufbau-principle, ionization
potential, ionic radii, VSEPR,
bond order, oxidation states |
|
9/2
|
4.3-4.4
4.9-4.12
5.1-5.4 |
121-123
131-140
148-154 |
4.14 + 4.17 + 5.11 + 5.22 |
4.5 + 4.12 |
Brønsted + lewis acid/base, HSAB,
oxidation, reduction, solvation |
|
16/2
|
6.1-6.5 |
179-191 |
6.1 + 6.3 + “Give examples of
symmetry for 3 macroscopic
items” |
6.3 + +”Discuss symmetry of the
d-orbitals” + Practise Figure
6.9 |
symmetry groups, labels,
elements, vibrations, isomerism,
chirality |
|
23/2
|
7.1.-7.15 |
199-220 |
7.1 + 7.4 + 7.5 + 7. 6 + 7.7 +
7. 9 + 7.10 + 7.14 |
7.4 + 7.10 |
Coord chem.: configurations,
ligands, nomenclature, coord.
numbers, isomerism, chelate
effect, formation constants |
|
2/3
|
8.1-8.10
+ “computational techniques” |
223-245
250-251 |
8.5 + 8.12 + 8.14 + 8.16 |
Suggest methods to study
complexes of Fe3+,Zn2+,Mn2+ |
X-ray, UV/IR/Raman, EPR, NMR,
Mössbauer ionization techniques,
DFT |
|
9/3
|
19.1-19.6
19.7-19.11 |
449-460
460-471 |
19.1 + 19.4 + 19.5 + 19.9 +
19.12 |
19.2 |
TM, occurrence, trends, halides,
oxides, sulfides, nitride,
metal-metal bonding |
|
16/3
|
20.1
20.2
20.5-20.6
20.8-20.9 |
473-483
483-487
497-501
502-504 |
20.1 + 20.4 + 20.5 + 20.8 +
20.14 + 20.22 |
20.8 + 20.10 |
crystal field theory,
spectrochem. series, LFSE, spin,
Jahn-Teller,ligand field, MLCT,
LMCT |
|
23/3
|
21.1-21.2
21.4
21.8-21.9
21.10-21.12 |
507-512
514-516
522-524
524-529 |
21.5 + 21.15 +
“Describe d-orbitals of Mn/Fe/Co/Ni
in 2+/3+ and Oh + Td
with respect to ET” |
21.5 + 21.6 |
ligand substitution: associate,
dissociative, interchange, trans
effect, steric effects, ET,
Irving-Williams, Marcus equation |
|
30/3
|
22.1-22.14
22.18-22.19
22.23-22.26 |
534-551
553-564
572-575 |
22.1 + 22.2 + 22.7 (Hint: Tabe
22.7)
22.12 + 22.20 |
22.6 + 22.8 |
organometallics, 18-electron
rule, 16 electron systems,
backbonding, carbonyls,
metallocenes, metathesis,
insertion |
|
13/4
|
26.1-26.8
26.10-26.16
|
690-703
704-716 |
26.2 + 26.3 + 26.4 + 26.9 +
26.12 |
26.1 + 26.2 |
catalytic cycle, turnover number,
homogeneous & heterogeneous
catalysis, Wilkinson’s/Ziegler-Natta
catalyst, selectivity |
|
20/4
|
27.1-27.2
27.3-27.6
27.7-27.8 |
722-731
731-738
738-745 |
27.2 + 27.3 + 27.5 |
27.2
+ Exam-type problems |
cell structure + elements in
life, amino acid & special
ligands, transport,
Transcription,
Mg/DNA, medicine |
|
27/4
|
27.9-27.11
27.17-27.21 |
745-763
772-778 |
27.6 + “Discuss use of Zn versus
Fe in enzymes” |
Exam-type problems |
Biocatalysis, enzymes with
metals, metals in medicine +
perspectives |
|
4/5
|
Read and prepare for questions
and “difficult topics” |
Repetition of previous exercises
+ exam problems |
Exam-type problems |
Repetition |
